Struvite Precipitation

Goal: By integrating vacuum degassing before mechanical dewatering, struvite can be specifically precipitated to reduce GHG emissions and improve the dewatering result.

The objectives of P-recycling from the sludgeliquor of sewage sludge and the operation of sludge dewatering leads to a conflict of interests. The main target of sludge dewatering is to reach optimal dewatering results due to high disposal costs. High concentrations of dissolved phosphate have a negative effect on the dewaterability of sewage sludge, but are necessary for phosphorus recycling. Also struvite precipitates in the centrate water pipes with a high phosphate level in the sewage sludge. The high pressure inside modern dewatering decanters dissolves more CO2 into the sludge and pH value of the sludge inside the bowl decreases. Laboratory tests showed that the Mg²⁺ concentration in the sludge liquor increases as pH decreases. Upon relaxation to ambient pressure after centrifugation, CO₂ is stripped out, causing the pH to rise and leading to struvite precipitation.


Through targeted crystallization tests, KBKopp can determine the optimal operating point based on temperature and magnesium and calcium concentrations, enabling trouble-free dewatering.
Incorporating vacuum degassing allows for the targeted precipitation of SP before mechanical dewatering. Thisprocess reduces GHG emissions and improves dewatering efficiency.

Source: KB Kopp

KBKopp can conduct preliminary tests and providesupport for large-scale trials.